4. Kiki Harrison, 'America's Sweethearts'
You can't hate on a female character who was supposed to be overweight and unattractive at one point in her life -- it's just one of the laws of rom-coms. And once you've seen them in their fat suit, all bets are off. Sympathy points! Kiki is the pushed-around assistant to her mega-star sister Gwen (Catherine Zeta-Jones
), and more than half of her charm comes from the fact that she is NOT Gwen, who is a selfish, vain diva. Kiki has her hair up, wears drab sweaters, and is a nice, unglamorous person. In rom-com world, she's a hero.